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Any errors in the above post are mine, and mine alone. Simplistic, unscientific explanation. The idea of stickyness, while easy to understand, does more to mislead than it does to truly educate. From time to time, we're unable to finish the entire bottle ourselves but don't want to share with others. This results in having to either hide the bottle or freeze it, which would both be pointless. People could always find where you're hiding your bottle, and nobody seems to know why alcohol doesn't freeze.
There are two main reasons why alcohol doesn't freeze. The main reason would be due to the fact that in most alcohol is a substance called ethanol. The higher the proof of a given alcohol, the lower the freezing point — in other words, higher alcoholic concentration makes a spirit harder to freeze. The freezing point of most alcohol is far below what our puny home freezers can handle they're generally set at zero degrees Fahrenheit or Celsius [source: FDA ].
A bottle of proof Everclear has a freezing point of Eighty-proof vodka freezes at But if you lower the alcohol content and raise the freezing point, you could end up with a freezer disaster if you don't play your cards right or a tasty frozen cocktail if you do. Wine is 85 to 90 percent water, so it freezes at about 20 F It'll be slushy for a while before it becomes solid.
A word to the wise: Don't freeze wine in the bottle. Water expands when it freezes, so the pressure could cause the bottle to crack and the cork to be pushed out. Beer, which is only about 10 proof and also mostly water, can cause a similar catastrophe. If you forget about a can or bottle in the freezer for a day or two, the water could expand enough to pop the bottle tops or explode the cans. If you're looking to use the freezer to create an alcoholic slushy or frozen drink, do yourself a favor and consult a recipe.
For instance, a recipe for slushy strawberry margaritas calls for four hours of freezing in a nonmetal freezer container, stirring the mixture halfway through.
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